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Iron Powder


   Contact Information:
   MiniScience, Inc.1059 Main Ave.,Clifton, NJ 07011
    
   1. Product Identification
   2. Composition/Information on Ingredients
   3. Hazards Identification
   4. First Aid Measures
   5. Fire Fighting Measures
   6. Accidental Release Measures
   7. Handling and Storage
   8. Exposure Controls/Personal Protection
   9. Physical and Chemical Properties
   10. Stability and Reactivity
   11. Toxicological Information
   12. Ecological Information
   13. Disposal Considerations
   14. Transport Information
   15. Regulatory Information
   16. Other Information

IRON POWDER


Contact Information:

 

MiniScience, Inc.
1059 Main Ave.,
Clifton, NJ 07011

 

 

 

1. Product Identification

 
Synonyms: Iron Dust; Iron Metal; Iron Powder.
CAS No.: 7439-89-6
Molecular Weight: 55.84
Chemical Formula: Fe 

2. Composition/Information on Ingredients

 
  Ingredient                                  CAS No        Percent     EINECS/ELINCS
  ---------------------------------------   ------------   ------------   ---------

  Iron powder, -325 Mesh                    7439-89-6        >97 %        231-096-4


3. Hazards Identification

 
Emergency Overview
--------------------------
Warning! May cause blood abnormalities. Inhalation of fumes may cause metal-fume fever. May cause lung damage. May cause cardiac disturbances. May cause liver damage. May cause mechanical eye and skin irritation. Moisture sensitive. Flammable solid.

-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate
Flammability Rating: 2 - Moderate
Reactivity Rating: 0 - None
Contact Rating: 
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code:  
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause lung damage.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Acute toxicity may include weakness, shock, cyanosis and acidosis. Delayed symptoms may include liver damage.
Skin Contact:
May cause skin irritation.
Eye Contact:
Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. Deposition of particles may cause corneal discoloration.
Chronic Exposure:
Chronic exposure may lead to liver and lung damage. Repeated exposure may cause pancreatic damage, diabetes, and cardiac abnormalities. Chronic exposure may lead to chronic bronchitis and a benign pneumoconiosis (siderosis).
Aggravation of Pre-existing Conditions:
None information found.

4. First Aid Measures

 
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Skin Contact:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Antidote:
The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.

5. Fire Fighting Measures

 
Flash Point:
Moderate fire hazard in form of dust when exposed to heat or flame. Can react with water to liberate flammable hydrogen gas. Minimum ignition temperature, iron dust cloud: 430C (805F). Ultrafine iron powder (ca. 5 microns) is pyrophoric and can ignite spontaneously in air.
Explosion:
Moderate explosion hazard in the form of a dust when exposed to heat or flame.
Fire Extinguishing Media:
Use only graphite powder, soda ash, powdered sodium chloride, or an appropriate metal-fire-extinguishing dry powder.
Special Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Combustion generates toxic fumes. Flammable solid.

6. Accidental Release Measures

 
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.



7. Handling and Storage

 
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Avoid dust formation and control ignition sources. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

 
Airborne Exposure Limits:
- OSHA Permissible Exposure Limit (PEL) -
Iron oxide fume: 10 mg/m3
- ACGIH Threshold Limit Value (TLV) -
Iron oxide dust and fume (Fe2O3) as Fe: 5 mg/m3 (TWA); inhalable particulate: A4 - Not classifiable as a human carcinogen.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.

9. Physical and Chemical Properties

 
Appearance:
Gray crystalline chips.
Odor:
No information found.
Solubility:
Insoluble, can react with water.
Specific Gravity:
7.86 @ 20C (68F)
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
2750C (4982F)
Melting Point:
1535C (2795F)
Vapor Density (Air=1):
Not applicable.
Vapor Pressure (mm Hg):
1 @ 1787C (3249F)
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

 
Stability:
Stable in dry air but readily oxidizes in moist air forming rust. Ultrafine (ca. 5 microns) powder forms are very unstable and can ignite spontaneously in air.
Hazardous Decomposition Products:
May produce toxic iron oxide fumes when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers, water (including humid atmospheres), acids, hydrogen peroxide, nitrogen dioxide. Solid or powdered iron ignites or explodes on contact with acetaldehyde, ammonium peroxodisulfate, chloroformamidinium, chloric acid, ammonium nitrate, halogens, dinitrogen tetraoxide, nitryl fluoride, polystyrene, sodium acetylide, potassium dichromate, peroxyformic acid, and nitryl fluoride. Hot iron wire burns in chlorine gas. Chlorine trifluoride reacts with iron with incandescence.
Conditions to Avoid:
Heat, flame, ignition sources, dusting and incompatibles.

11. Toxicological Information

 

Oral rat LD50: 30 gm/kg; investigated as a tumorigen.
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Iron Reduced (7439-89-6)                No          No            None

12. Ecological Information

 
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

 
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

 
Not regulated.

15. Regulatory Information

 
  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Iron Reduced (7439-89-6)                          Yes  Yes   No       Yes

  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Iron Reduced (7439-89-6)                          Yes   Yes   No     Yes

  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Iron Reduced (7439-89-6)                   No    No      No         No

  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)
  -----------------------------------------  ------     ------    ------
  Iron Reduced (7439-89-6)                   No         No         No


Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)


Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

 
NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 1
Label Hazard Warning:
CAUTION! MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Avoid breathing dust.
Keep container closed.
Use with adequate ventilation.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Product Use:
Laboratory Reagent.
Revision Information:
Feb. 2004.
Disclaimer:
************************************************************************************************ 
MiniScience, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MINISCIENCE, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MINISCIENCE WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
********************************************************************************


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