Section 1 - Chemical Product and Company Identification
MSDS Name: Iodine Solutions 1N and Lugol Catalog Numbers: IODINE_S29, Lugol29 Synonyms: None Company Identification: MiniScience Inc. (ChemicalStore.com) 1059 Main Avenue, Clifton, NJ 07011 For information, call: 973-777-3113 Emergency Number: 973-405-6248 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
Hazard Symbols: XN Risk Phrases: 22
Section 3 - Hazards Identification
Appearance: dark amber. Caution! May cause eye and skin irritation. May cause respiratory and digestive tract irritation. Target Organs: Central nervous system, respiratory system, cardiovascular system.
Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause gastric disturbances and electrolytic imbalance. Inhalation: May cause respiratory tract irritation. Chronic: Chronic exposure can lead to iodism characterized by salivation, nasal discharge, sneezing, conjunctivitis, fever, laryngitis, bronchitis, stomatitis, and skin rashes.
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. Get medical aid if cough or other symptoms appear. Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Storage: Store in a cool, dry place.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits
OSHA - Final PELs
C 0.1 ppm
2 ppm IDLH
C 0.1 ppm; C 1 mg/m3
OSHA Vacated PELs: Iodine: C 0.1 ppm; C 1 mg/m3 Potassium iodide: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR �1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Section 9 - Physical and Chemical Properties
Physical State: Liquid Appearance: dark amber Odor: iodine-like pH: Not available. Vapor Pressure: 14 mm Hg Vapor Density: 0.7 Evaporation Rate:>1 Viscosity: Not available. Boiling Point: 100 deg C Freezing/Melting Point:0 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Decomposition Temperature:Not available. NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0 Explosion Limits, Lower:Not available. Upper: Not available. Solubility: Soluble in water. Specific Gravity/Density:1.0 Molecular Formula:Not applicable. Molecular Weight:Not available.
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Powdered aluminum, active metals, strong reducing agents. Acetylene and acetaldehyde causes explosive reactions with iodine. Mixtures with ammonium hydroxide form shock sensitive compounds. Hazardous Decomposition Products: Hydrogen iodide, iodine, iodide ions (I-). Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
RTECS#: CAS# 7553-56-2: NN1575000 CAS# 7681-11-0: TT2975000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg; CAS# 7681-11-0: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; Carcinogenicity: CAS# 7553-56-2: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7681-11-0: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: No data available. Teratogenicity: Potassium iodide has been observed to cause developmental abnormalities of the endocrine system in human fetuses. Reproductive Effects: No data available. Neurotoxicity: No data available. Mutagenicity: No data available. Other Studies: No data available.
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